Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/24707
Registo completo
Campo DC | Valor | Idioma |
---|---|---|
dc.contributor.author | Duñach, E. | - |
dc.contributor.author | Medeiros, M. J. | - |
dc.contributor.author | Olivero, S. | - |
dc.date.accessioned | 2013-07-16T13:14:55Z | - |
dc.date.available | 2013-07-16T13:14:55Z | - |
dc.date.issued | 2013-04-27 | - |
dc.identifier.issn | 0013-4651 | por |
dc.identifier.uri | https://hdl.handle.net/1822/24707 | - |
dc.description.abstract | The electrochemical intramolecular cyclisation of bromoalkoxylated derivatives 1 was carried out using Ni(II) complexes as the catalysts in ethanol solutions by constant-current electrolysis in one-compartment cell in the absence of sacrificial anodes as an environmentally friendly system. The reduction of the substrates proceeds via one-electron cleavage of the carbon–bromine bond to form radical-type intermediates that undergo cyclisation to afford cyclic ethers in moderate to good yields. | por |
dc.description.sponsorship | Fundação para a Ciência e a Tecnologia (FCT) | por |
dc.language.iso | eng | por |
dc.publisher | The Electrochemical Society | por |
dc.rights | openAccess | por |
dc.subject | Cyclization | por |
dc.subject | Nickel(II) complex | por |
dc.subject | Electroreduction | por |
dc.subject | Heterocycles | por |
dc.subject | Ethanol solvent | por |
dc.title | Electrochemical catalytic cyclization reactions using environmentally friendly methodologies | por |
dc.type | article | por |
dc.peerreviewed | yes | por |
dc.relation.publisherversion | http://dx.doi.org/10.1149/2.016307jes | por |
sdum.publicationstatus | published | por |
oaire.citationStartPage | G3112 | por |
oaire.citationEndPage | G3116 | por |
oaire.citationIssue | 7 | por |
oaire.citationTitle | Journal of The Electrochemical Society | por |
oaire.citationVolume | 160 | por |
dc.identifier.doi | 10.1149/2.016307jes | por |
dc.subject.wos | Science & Technology | por |
sdum.journal | Journal of The Electrochemical Society | por |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
---|---|---|---|---|
MJM-paper final-JES 2013-MJM.pdf | documento principal | 327,29 kB | Adobe PDF | Ver/Abrir |