Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/49313
Título: | Heterocyclic imidazo-anthraquinone as an optical sensor: synthesis, characterization and evaluation of the chemosensory ability |
Autor(es): | Ferreira, Rosa Cristina Moutinho Costa, Susana P. G. Raposo, M. Manuela M. |
Palavras-chave: | Optical chemosensor Imidazole Anthraquinone Ion sensing Imidazo-anthraquinone Thiophene Colorimetric sensor “naked - eye” detection Aqueous media |
Data: | Nov-2017 |
Citação: | Proceedings of the 21st Int. Electron. Conf. Synth. Org. Chem., 1–30 November 2017; Sciforum Electronic Conference Series, Vol. 21, 2017; doi:10.3390/ecsoc-21-04796. |
Resumo(s): | A novel imidazo-anthraquinone derivative 3 was synthesized in moderate yield. The photophysical properties of the new compound were studied by UV-vis and fluorescence spectroscopy in ACN. The evaluation of the new compound as a colorimetric chemosensor was carried out by performing spectrophotometric titrations in ACN and ACN/H2O in the presence of relevant organic and inorganic anions and transition metal cations. Imidazo-anthraquinone 3 exhibited great selectivity for the cyanide anion over other anions in ACN/H2O (95:5) solution showing a distinct color change from yellow to pink. |
Tipo: | Artigo em ata de conferência |
URI: | https://hdl.handle.net/1822/49313 |
DOI: | 10.3390/ecsoc-21-04796 |
Versão da editora: | http://sciforum.net/conference/ecsoc-21/paper/4796 |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Comunicações e Proceedings |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Proceeding 2 ECSOC 2017 repositorium.pdf | 661,63 kB | Adobe PDF | Ver/Abrir |