Please use this identifier to cite or link to this item: https://hdl.handle.net/1822/79324

TitleActive neutralizing mats for corrosive chemical storage
Author(s)Fernandes, Rui Daniel Vilaça
Melro, Liliana Sofia Silva Ferreira Pinto
Padrão, Jorge
Ribeiro, Ana Isabel Ferreira
Mehravani, Behnaz
Monteiro, Filipa Maria Barbosa Faria
Pereira, E. N. B.
Martins, Marcos Silva
Dourado, N.
Zille, Andrea
KeywordsNeutralizing mats
Chemical storage
Composite mats
Alginate
Sodium carbonate
Citric acid
Issue date2022
PublisherMDPI
JournalGels
Abstract(s)Laboratories and industries that handle chemicals are ubiquitously prone to leakages. These may occur in storage rooms, cabinets or even in temporary locations, such as workbenches and shelves. A relevant number of these chemicals are corrosive, thus commercial products already exist to prevent material damage and injuries. One strategy consists of the use of absorbing mats, where few display neutralizing properties, and even less a controlled neutralization. Nevertheless, to the authors’ knowledge, the commercially available neutralizing mats are solely dedicated to neutralizing acid or alkali solutions, never both. Therefore, this work describes the development and proof of a completely novel concept, where a dual component active mat (DCAM) is able to perform a controlled simultaneous neutralization of acid and alkali leakages by using microencapsulated active components. Moreover, its active components comprise food-grade ingredients, embedded in nonwoven polypropylene. The acid neutralizing mats contain sodium carbonate (Na2CO3 ) encapsulated in sodium alginate microcapsules (MC-ASC). Alkali neutralizing mats possess commercial encapsulated citric acid in hydrogenated palm oil (MIRCAP CT 85-H). A DCAM encompasses both MC-ASC and MIRCAP CT 85-H and was able to neutralize solutions up to 10% (v/v) of hydrochloric acid (HCl) and sodium hydroxide (NaOH). The efficacy of the neutralization was assessed by direct titration and using pH strip measurement tests to simulate the leakages. Due to the complexity of neutralization efficacy evaluation based solely on pH value, a thorough conductivity study was performed. DCAM reduced the conductivity of HCl and NaOH (1% and 2% (v/v)) in over 70%. The composites were characterized by scanning electron microscopy (SEM), differential calorimetry (DSC) and thermogravimetric analysis (TGA). The size of MC-ASC microcapsules ranged from 2 µm to 8 µm. Finally, all mat components displayed thermal stability above 150 ◦C.
TypeArticle
URIhttps://hdl.handle.net/1822/79324
DOI10.3390/gels8080489
Peer-Reviewedyes
AccessOpen access
Appears in Collections:DET/2C2T - Artigos em revistas internacionais com arbitragem científica

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