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https://hdl.handle.net/1822/80267| Título: | Synthesis of novel sugar derived aziridines, as starting materials giving access to sugar amino acid derivatives |
| Autor(es): | Sousa, Cristina E.A. Alves, Maria José Chão |
| Palavras-chave: | Aziridines D-Erythrose Diazirines Polyhydroxyprolines Sugar aminoacids |
| Data: | Jul-2021 |
| Editora: | Springer |
| Revista: | Amino Acids |
| Citação: | Sousa, C.E.A., Alves, M.J. Synthesis of novel sugar derived aziridines, as starting materials giving access to sugar amino acid derivatives. Amino Acids 53, 1123–1134 (2021). https://doi.org/10.1007/s00726-021-03017-4 |
| Resumo(s): | d-Erythrosyl aziridines were obtained from d-erythrosyl triazoles either by photolysis or through diazirine intermediates. These were found to undergo rich, high yielding chemistry by reaction with protic acids (HCl, BiI3/H2O and trifluoroacetic acid) leading to two types of furanoid sugar α-amino acids, and polyhydroxylprolines. Based on experimental evidence, reaction mechanisms have been proposed for the syntheses. |
| Tipo: | Artigo |
| URI: | https://hdl.handle.net/1822/80267 |
| DOI: | 10.1007/s00726-021-03017-4 |
| ISSN: | 0939-4451 |
| e-ISSN: | 1438-2199 |
| Versão da editora: | https://link.springer.com/article/10.1007/s00726-021-03017-4 |
| Arbitragem científica: | yes |
| Acesso: | Acesso aberto |
| Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
| Ficheiro | Descrição | Tamanho | Formato | |
|---|---|---|---|---|
| Sousa-Alves_2021_Article.pdf | Synthesis of novel sugar derived aziridines, as starting materials giving access to sugar amino acid derivatives | 1,03 MB | Adobe PDF | Ver/Abrir |
