Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/82144
Título: | Humidity sensors based on magnetic ionic liquids blended in poly(vinylidene fluoride-co-hexafluoropropylene) |
Autor(es): | Serra, João P. Fernandes, Liliana C. Pereira, Nelson Fidalgo-Marijuan, Arkaitz Porro, José M. Costa, Carlos Miguel Silva Correia, Daniela Maria Silva Lanceros-Méndez, S. |
Palavras-chave: | Composites, Ionic liquids PVDF-HFP Smart materials Humidity sensor composites ionic liquids |
Data: | 2023 |
Editora: | American Chemical Society (ACS) |
Revista: | ACS Applied Polymer Materials |
Citação: | Serra, J. P., Fernandes, L. C., Pereira, N., Fidalgo-Marijuan, A., Porro, J. M., Costa, C. M., … Lanceros-Mendez, S. (2023). Humidity Sensors Based on Magnetic Ionic Liquids Blended in Poly(vinylidene fluoride-co-hexafluoropropylene). ACS Applied Polymer Materials. American Chemical Society (ACS). http://doi.org/10.1021/acsapm.2c01303 |
Resumo(s): | Poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) films incorporating 40 %wt. of different types of imidazolium ionic liquids (ILs) comprising different magnetic anions (tetrachloroferrate [FeCl4] - , tetrathiocyanatocobaltate [(SCN)4Co]2 - and tetrachlorocobaltate [CoCl4] - ) and imidazolium cation chain lengths 1-butyl-3-methyl imidazolium and 1-ethyl-3-methyl imidazolium, have been developed for humidity sensing applications. The influence of the different ILs into the morphology of the IL/PVDF-HFP composites has been evaluated, being observed a porous structure independently of the IL anion type and cation chain length. The inclusion of the ILs into PVDF-HFP induces the polymer crystallization into the electroactive β phase, being the increase more noticeable for PVDF-HFP/[Bmim][FeCl4], which reaches a β phase content of 85%. The degree of crystallinity slightly decreases with the incorporation of the filler, the incorporation of [Bmim]2[CoCl4], [Bmim]2[Co(SCN)4], and [Emim]2[Co(SCN)4] leading to a degree of crystallinity between 11 and 13%. A decrease in the thermal stability and the yield strength is observed in the hybrid samples with respect to neat PVDF-HFP, being this decrease more noticeable for the PVDF-HFP/[Bmim]2[Co(SCN)4] samples. Further, the highest magnetization has been obtained for the PVDF-HFP/[Bmim]2[Co(SCN)4] and PVDF-HFP/[Bmim][FeCl4] composites with similar filler concentrations. The suitability of the developed materials for humidity sensing has been evaluated by analysing the impedance variation with varying relative humidity from 30% to 85%. [Bmim]2[CoCl4]/PVDF-HFP displays the highest relative humidity (RH) sensing response of -2245 ±240 Ω/RH. Finally, the applicability of the developed hybrid IL/polymer composites has been demonstrated by the development of a real time breathing monitoring device. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/82144 |
DOI: | 10.1021/acsapm.2c01303 |
ISSN: | 2637-6105 |
Versão da editora: | https://pubs.acs.org/doi/full/10.1021/acsapm.2c01303 |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
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Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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69.pdf Acesso restrito! | 1,59 MB | Adobe PDF | Ver/Abrir |