Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/31988
Título: | Poly(vinylidene fluoride)-based, co-polymer separator electrolyte membranes for lithium-ion battery systems |
Autor(es): | Costa, C. M. Gomez Ribelles, J. L. Lanceros-Méndez, S. Appetecchi, G. B. Scrosati, B. |
Palavras-chave: | Poly(vinylidene fluoride) copolymers Polymeric blends Gel polymer electrolytes Lithium battery applications |
Data: | Jan-2014 |
Editora: | Elsevier 1 |
Revista: | Journal of Power Sources |
Citação: | Costa, C. M., Gomez Ribelles, J. L., Lanceros-Méndez, S., Appetecchi, G. B., & Scrosati, B. (2014). Poly (vinylidene fluoride)-based, co-polymer separator electrolyte membranes for lithium-ion battery systems. Journal of Power Sources, 245, 779-786. |
Resumo(s): | In the present paper we report and discuss the physicochemical properties of novel electrolyte membranes, based on poly(vinylidenefluoride-co-trifluoroethylene), PVdF-TrFE, and poly(vinylidenefluorideco- hexafluoropropylene), PVdF-HFP, co-polymer hosts and the PVdF-TrFE/poly(ethylene oxide (PEO) blend as separators for lithium battery systems. The results have shown that the examined separator membranes, particularly those based on the PVdF co-polymers, are able to uptake large liquid amounts leading to high ionic conductivity values. Tests performed on Li/LiFePO4 and Li/SneC cells have revealed very good cycling performance even at high current rates and 100% of DOD, approaching the results achieved in liquid electrolytes. A capacity fading lower than 0.002% per cycle was observed. Particularly, the Li/LiFePO4 cathode cells have exhibited excellent rate capability, being still able to deliver at 2C above 89% of the capacity discharged at 0.1C. These results, in conjunction with the about 100% coulombic efficiency, suggest very good electrolyte/ electrode compatibility, which results from the high purity and stability of the electrolyte and electrode materials and the cell manufacturing. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/31988 |
DOI: | 10.1016/j.jpowsour.2013.06.151 |
ISSN: | 0378-7753 |
Versão da editora: | http://www.sciencedirect.com/science/article/pii/S0378775313011580 |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
Aparece nas coleções: | CDF - FCD - Artigos/Papers (with refereeing) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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electrolyte membranes.pdf Acesso restrito! | electrolyte membranes | 1,57 MB | Adobe PDF | Ver/Abrir |