Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/32292
Título: | Study of novel lithium salt-based, plasticized polymer electrolytes |
Autor(es): | Silva, Maria Manuela Barros, Sandra Cerqueira Smith, Michael John MacCallum, James R. |
Palavras-chave: | Polymer electrolytes Conductivity Thermal analysis Plasticizer lithium perchlorate lithium triflate plasticizers |
Data: | Abr-2002 |
Editora: | Elsevier 1 |
Revista: | Journal of Power Sources |
Resumo(s): | The results of a preliminary investigation of a series of polymer electrolytes based on a novel polymer host, poly(trimethylene carbonate) or p(TMC), with lithium triflate or lithium perchlorate and various plasticizing additives, are described in this presentation. Electrolytes with lithium salt compositions of about n = 10 (where n represents the molar ratio of (O=COCH2CH2CH2O) units per lithium ion) and additive compositions between 5 and 15 wt% (with respect to p(TMC)), were prepared by co-dissolution of salt and polymer in anhydrous solvent with a controlled amount of additive. The homogeneous solutions obtained were evaporated within a preparative glovebox and under a dry argon atmosphere to form thin films of electrolyte. The solvent-free electrolyte films produced were characterized by measurements of total ionic conductivity, differential scanning calorimetry and thermogravimetry. In general the triflate-based electrolytes were found to show moderate ionic conductivity and good thermal stability while perchlorate-based electrolytes showed higher levels of conductivity but lower thermal stability. Electrolytes based on this host polymer, with both lithium salts, were obtained as very flexible, transparent, completely amorphous films. |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/32292 |
DOI: | 10.1016/S0378-7753(02)00229-X |
ISSN: | 0378-7753l |
Versão da editora: | The original publication is available at www.elsevier.com |
Arbitragem científica: | yes |
Acesso: | Acesso aberto |
Aparece nas coleções: | CDQuim - Artigos (Papers) |