Utilize este identificador para referenciar este registo:
https://hdl.handle.net/1822/31819
Título: | Selective colorimetric and fluorimetric detection of cyanide in aqueous solution using novel heterocyclic imidazo-anthraquinones |
Autor(es): | Batista, Rosa Maria Ferreira Costa, Susana P. G. Raposo, M. Manuela M. |
Palavras-chave: | colorimetric and fluorimetric chemosensors synthesis imidazole anthraquinone heterocycles cyanide aqueous media naked-eye detection |
Data: | 16-Jan-2014 |
Editora: | Elsevier 1 |
Revista: | Sensors & Actuators B: Chemical |
Citação: | Batista, R. M. F., Costa, S. P. G., & Raposo, M. M. M. (2014). Selective colorimetric and fluorimetric detection of cyanide in aqueous solution using novel heterocyclic imidazo-anthraquinones. Sensors and Actuators B-Chemical, 191, 791-799. doi: 10.1016/j.snb.2013.10.030 |
Resumo(s): | Novel receptors based on imidazo-anthraquinone system containing thiazole, (benzo)furan, thiophene and imidazole heterocycles at position 2 were synthesized. The photophysical properties of compounds 1-8 were studied by UV-vis and fluorescence spectroscopy in acetonitrile. All anthraquinone derivatives exhibited great selectivity for the cyanide anion over other anions in acetonitrile/water (9:1) solution showing a distinct colour change from yellow to orange and the fluorescence emission was switched “off”. The binding stoichiometry between the receptors and the anions was found to be 1:1. Moreover, chemosensors 1-8 exhibit a high sensitivity being capable to detect cyanide in very low concentrations (below 4 microM). |
Tipo: | Artigo |
URI: | https://hdl.handle.net/1822/31819 |
DOI: | 10.1016/j.snb.2013.10.030 |
ISSN: | 0925-4005 |
Arbitragem científica: | yes |
Acesso: | Acesso restrito UMinho |
Aparece nas coleções: | CDQuim - Artigos (Papers) |
Ficheiros deste registo:
Ficheiro | Descrição | Tamanho | Formato | |
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Sensors actuators-2014.pdf Acesso restrito! | Documento principal | 860,09 kB | Adobe PDF | Ver/Abrir |