A BGK model for reactive mixtures of polyatomic gases with continuous internal energy

Abstract

In this paper we derive a BGK relaxation model for a mixture of polyatomic gases with a continuous structure of internal energies. The emphasis of the paper is on the case of a quaternary mixture undergoing a reversible chemically reaction of bimolecular type. For such a mixture we prove an H-theorem and characterize the equilibrium solutions with related mass action law of chemical kinetics. Further, a Chapman-Enskog asymptotic analysis is performed in view of computing the first-order non-equilibrium corrections to the distribution functions and investigating the transport properties of the reactive mixture. The chemical reaction rate is explicitly derived at the first-order and the balance equations for the constituent number densities are derived at the Euler level.