New benzo[a]phenoxazines bearing the (4,6-dichloro-1,3,5-triazin-2-yl)amino group: synthesis and photophysical properties
| dc.contributor.author | Raju, B. Rama | por |
| dc.contributor.author | Parente, Joana F. C. | por |
| dc.contributor.author | Leitão, Maria Inês P. S. | por |
| dc.contributor.author | Coutinho, Paulo J. G. | por |
| dc.contributor.author | Gonçalves, M. Sameiro T. | por |
| dc.date.accessioned | 2018-01-25T11:57:04Z | |
| dc.date.available | 2018-01-25T11:57:04Z | |
| dc.date.issued | 2015-11 | |
| dc.description.abstract | Synthesis of new benzo[a]phenoxazinium chlorides possessing the (4,6-dichloro-1,3,5- triazin-2-yl)amino at 5-amino function of the heterocycles is described. The preliminary photophysical properties of these compounds in anhydrous ethanol when acidified with TFA or basified with TEAH is also investigated, as well as their response in aqueous media. These benzo[a]phenoxazinium chlorides exhibited fluorescence with maximum emission wavelengths between 628 and 676 nm, in anhydrous ethanol and water. | por |
| dc.description.publicationversion | info:eu-repo/semantics/publishedVersion | por |
| dc.description.sponsorship | Thanks are due to the Fundação para a Ciência e Tecnologia (FCT, Portugal) for financial support to the NMR portuguese network (PTNMR, Bruker Avance III 400-Univ. Minho), FCT and FEDER (European Fund for Regional Development)-COMPETE-QREN-EU for financial support to the Research Centres CFUM [PEst-C/FIS/UI0607/2011 (F-COMP-01-0124-FEDER-022711)] and CQ/UM [PEst-C/QUI/UI0686/2013(FCOMP-01-0124-FEDER-022716)]. A post-doctoral grant to B. R. Raju (SFRH/BPD/62881/2009) is also acknowledged to FCT, POPH-QREN, FSE. | por |
| dc.distribution | international | por |
| dc.identifier.citation | Sciforum Electronic Conference Series, Vol. 19, 2015, a012 | por |
| dc.identifier.doi | 10.3390/ecsoc-19-a012 | por |
| dc.identifier.uri | https://hdl.handle.net/1822/49696 | |
| dc.language.iso | eng | por |
| dc.peerreviewed | yes | por |
| dc.publisher | Sciforum Electronic Conferences Series | por |
| dc.relation | info:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F62881%2F2009/PT | por |
| dc.relation | info:eu-repo/grantAgreement/FCT/COMPETE/132953/PT | por |
| dc.relation | PEst-C/FIS/UI0607/2011 | por |
| dc.relation.publisherversion | https://sciforum.net/conference/ecsoc-19/paper/3037 | por |
| dc.rights | openAccess | por |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/4.0/ | por |
| dc.subject | Benzo[a]phenoxazinium dyes | por |
| dc.subject | Nile Blue | por |
| dc.subject | 2,4,6-trichloro-1,3,5-triazine | por |
| dc.subject | Acid-base equilibrium | por |
| dc.subject.fos | Ciências Naturais::Ciências Químicas | por |
| dc.subject.wos | Science & Technology | por |
| dc.title | New benzo[a]phenoxazines bearing the (4,6-dichloro-1,3,5-triazin-2-yl)amino group: synthesis and photophysical properties | por |
| dc.type | conferencePaper | por |
| dspace.entity.type | Publication | en |
| oaire.citationEndPage | a012 | por |
| oaire.citationIssue | 2015 | por |
| oaire.citationStartPage | a012 | por |
| oaire.citationVolume | 19 | por |
| sdum.bookTitle | 19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRY | por |
| sdum.conferencePublication | Proceedings of the 19th Int. Electron. Conf. Synth. Org. Chem |
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