New benzo[a]phenoxazines bearing the (4,6-dichloro-1,3,5-triazin-2-yl)amino group: synthesis and photophysical properties

dc.contributor.authorRaju, B. Ramapor
dc.contributor.authorParente, Joana F. C.por
dc.contributor.authorLeitão, Maria Inês P. S.por
dc.contributor.authorCoutinho, Paulo J. G.por
dc.contributor.authorGonçalves, M. Sameiro T.por
dc.date.accessioned2018-01-25T11:57:04Z
dc.date.available2018-01-25T11:57:04Z
dc.date.issued2015-11
dc.description.abstractSynthesis of new benzo[a]phenoxazinium chlorides possessing the (4,6-dichloro-1,3,5- triazin-2-yl)amino at 5-amino function of the heterocycles is described. The preliminary photophysical properties of these compounds in anhydrous ethanol when acidified with TFA or basified with TEAH is also investigated, as well as their response in aqueous media. These benzo[a]phenoxazinium chlorides exhibited fluorescence with maximum emission wavelengths between 628 and 676 nm, in anhydrous ethanol and water.por
dc.description.publicationversioninfo:eu-repo/semantics/publishedVersionpor
dc.description.sponsorshipThanks are due to the Fundação para a Ciência e Tecnologia (FCT, Portugal) for financial support to the NMR portuguese network (PTNMR, Bruker Avance III 400-Univ. Minho), FCT and FEDER (European Fund for Regional Development)-COMPETE-QREN-EU for financial support to the Research Centres CFUM [PEst-C/FIS/UI0607/2011 (F-COMP-01-0124-FEDER-022711)] and CQ/UM [PEst-C/QUI/UI0686/2013(FCOMP-01-0124-FEDER-022716)]. A post-doctoral grant to B. R. Raju (SFRH/BPD/62881/2009) is also acknowledged to FCT, POPH-QREN, FSE.por
dc.distributioninternationalpor
dc.identifier.citationSciforum Electronic Conference Series, Vol. 19, 2015, a012por
dc.identifier.doi10.3390/ecsoc-19-a012por
dc.identifier.urihttps://hdl.handle.net/1822/49696
dc.language.isoengpor
dc.peerreviewedyespor
dc.publisherSciforum Electronic Conferences Seriespor
dc.relationinfo:eu-repo/grantAgreement/FCT/SFRH/SFRH%2FBPD%2F62881%2F2009/PTpor
dc.relationinfo:eu-repo/grantAgreement/FCT/COMPETE/132953/PTpor
dc.relationPEst-C/FIS/UI0607/2011por
dc.relation.publisherversionhttps://sciforum.net/conference/ecsoc-19/paper/3037por
dc.rightsopenAccesspor
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/por
dc.subjectBenzo[a]phenoxazinium dyespor
dc.subjectNile Bluepor
dc.subject2,4,6-trichloro-1,3,5-triazinepor
dc.subjectAcid-base equilibriumpor
dc.subject.fosCiências Naturais::Ciências Químicaspor
dc.subject.wosScience & Technologypor
dc.titleNew benzo[a]phenoxazines bearing the (4,6-dichloro-1,3,5-triazin-2-yl)amino group: synthesis and photophysical propertiespor
dc.typeconferencePaperpor
dspace.entity.typePublicationen
oaire.citationEndPagea012por
oaire.citationIssue2015por
oaire.citationStartPagea012por
oaire.citationVolume19por
sdum.bookTitle19TH INTERNATIONAL ELECTRONIC CONFERENCE ON SYNTHETIC ORGANIC CHEMISTRYpor
sdum.conferencePublicationProceedings of the 19th Int. Electron. Conf. Synth. Org. Chem

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